Genre
- Journal Article
Contributors
Author: Epp, Karen M.
Author: Abd-El-Aziz, Alaa S.
Date Issued
1995
Abstract
A unique synthetic route to cyclopentadienyliron complexes of functionalized nitrobenzene has been developed via the successive oxidation of the amine and the alkyl groups of their corresponding aniline complexes. Nucleophilic aromatic substitution reactions of the nitroarene complexes with a number of nucleophiles gave rise to monoiron and diiron complexes with various alkyl and keto substituents.
Note
Dep. Chem., Univ. Winnipeg, Winnipeg, MB, Can.
Language
- English
Subjects
- aniline
- peroxide
- Amines Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (complexes, oxidn. of η6-(alkylated aniline)(η5-cyclopentadienyl)iron complexes and subsequent nucleophilic arom. substitution reactions of the prod
- nucleophilic
- complex
- substitution
- iron
- hydrogen
- nitroarene
- arom
- cyclopentadienyliron
- Substitution reaction (oxidn. of η6-(alkylated aniline)(η5-cyclopentadienyl)iron complexes and subsequent nucleophilic arom. substitution reactions of the product nitroarene complexes)
- oxidn
Page range
957-960
Host Title
Polyhedron
Host Abbreviated Title
Polyhedron
Volume
14
Issue
7
ISSN
0277-5387