de Denus, Christine R., et al. “Building Blocks of Aromatic Ethers and Thioethers: Synthesis and Polymerization”. Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), Section Title: Chemistry of Synthetic High Polymers, vol. 39, no. 1, 1998, pp. 408-9, https://scholar2.islandarchives.ca/islandora/object/ir%3A1481.

Genre

  • Journal Article
Contributors
Author: de Denus, Christine R.
Author: Epp, Karen M.
Author: Abd-El-Aziz, Alaa S.
Date Issued
1998
Abstract

Displacement of the terminal chloro groups of diiron arene complexes with 1-naphthol led to the formation of the corresponding complex with terminal naphthoxy groups. Photolytic demetallation of these complexes produced the monomeric blocks in good yields. Scholl polymn. was implemented leading to the formation of polyarom. ethers and thioethers. The polymn. of various monomers has proven to be time and concn. dependent. [on SciFinder(R)]

Note

Department of Chemistry, The University of Winnipeg, Winnipeg, MB, Can.

Copyright (C) 2012 American Chemical Society (ACS). All Rights Reserved.; Section Code: 35-7; CODEN: ACPPAY; CAS Registry Numbers: 204905-76-0P; 204905-79-3P; 204905-83-9P; 204905-89-5P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (extension of cyclopentadienyl iron activation of chloroarene complexes toward nucleophilic arom. substitution as viable route for design of monomeric units suitable for Scholl polymn.); 204905-92-0P; 204905-96-4P; 204906-01-4P; 204906-04-7P Role: SPN (Synthetic preparation), PREP (Preparation) (extension of cyclopentadienyl iron activation of chloroarene complexes toward nucleophilic arom. substitution as viable route for design of monomeric units suitable for Scholl polymn.)

Language

  • English

Subjects

  • Polyethers Role: SPN (Synthetic preparation), PREP (Preparation) (polysulfide-
  • monomer
  • Polyethers
  • polyether
  • polysulfone
  • Polyethers Role: SPN (Synthetic preparation), PREP (Preparation) (extension of cyclopentadienyl iron activation of chloroarene complexes toward nucleophilic arom. substitution as viable route for design of monomeric units suitable for Scholl polymn.)
  • Polyethers Role: SPN (Synthetic preparation), PREP (Preparation) (polysulfone-
  • arom
  • Scholl
  • synthesis
  • Polysulfones Role: SPN (Synthetic preparation), PREP (Preparation) (polyether-
  • extension of cyclopentadienyl iron activation of chloroarene complexes toward nucleophilic arom. substitution as viable route for design of monomeric units suitable for Scholl polymn.)
  • bisnaphthyloxy
  • polysulfide
  • polymn
  • Polysulfides
  • Polysulfones
Page range
408-409
Host Title
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry)
Section Title: Chemistry of Synthetic High Polymers
Host Abbreviated Title
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.)
Volume
39
Issue
1
ISSN
0032-3934

Department