Kotowich, Steven, et al. “Innovative Approach to the Synthesis of Sulfides and Their Corresponding Sulfones”. Journal of Chemical Research, Synopses, no. 5, 1995, pp. 182-3, https://doi.org/10.1002/chin.199542107.

Genre

  • Journal Article
Contributors
Author: Kotowich, Steven
Author: Lei, Yun
Author: Epp, Karen M.
Author: Abd-El-Aziz, Alaa S.
Date Issued
1995
Abstract

Nucleophilic arom. substitution (SnAr) of cyclopentadienyliron-arene complexes with various aliph. or arom. dithiols followed by oxidn. and/or photolysis is presented as a viable route to the prepn. of the corresponding bis(sulfides) and bis(sulfones) in yields of 70-96%. The photochem. reaction of iron complexes I (R = H, alkyl, etc.; X = O, S; Cp = cyclopentadienyl) gave the sulfides II (same R, X).

Note

Dep. Chem., Univ. Winnipeg, Winnipeg, Can.

Language

  • English

Subjects

  • Sulfones Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of bis(sulfides) and bis(sulfones) from (cyclopentadienyl)iron-arene complexes)
  • sulfone
  • phenyl
  • sulfide
Page range
182-183
Host Title
Journal of Chemical Research, Synopses
Host Abbreviated Title
J. Chem. Res., Synop.
Issue
5
ISSN
0308-2342
DOI
https://doi.org/10.1002/chin.199542107

Department