de Denus, Christine R., et al. “1H NMR Analysis of Some η6-(substituted Aryl Phenylsulfonylacetonitrile)-η5-Cyclopentadienyliron Cations”. Inorganica Chimica Acta, vol. 219, no. 1-2, 1994, pp. 221-3, https://doi.org/10.1016/0020-1693(94)03830-9.

Genre

  • Journal Article
Contributors
Author: de Denus, Christine R.
Author: Hutton, Harold M.
Author: Hazendonk, Paul
Author: Abd-El-Aziz, Alaa S.
Date Issued
1994
Abstract

A detailed 1H NMR study of the title compds. I (R = Me, R1 = H; R = H, R1 = Cl) using difference NOE spectra and 2-D (COSY) techniques has shown that there is an enhanced restricted rotation about the arene-methine carbon bond with the formation of the complexes.

Note

Department of Chemistry, University of Winnipeg, Winnipeg, Man., R3B 2E9, Can.

Language

  • English

Subjects

  • Potential barrier (rotational, in aryl-substituted (phenylsulfonylacetonitrile)-η5-cyclopentadienyliron cations)
  • cation
  • Overhauser effect (of aryl-substituted (phenylsulfonylacetonitrile)-η5-cyclopentadienyliron cations)
  • rotation
  • areneiron
  • phenylsulfonylacetonitrile
  • Nuclear magnetic resonance
  • restricted
  • cyclopentadienyliron
  • NMR
Page range
221-223
Host Title
Inorganica Chimica Acta
Host Abbreviated Title
Inorg. Chim. Acta
Volume
219
Issue
1-2
ISSN
0020-1693
DOI
https://doi.org/10.1016/0020-1693(94)03830-9

Department