Sutherland, Ronald G., et al. “Arylation of Diethyl Malonate via Nucleophilic Substitution Reactions With Cyclopentadienyliron Complexes of Chloroarenes”. Synthetic Communications, vol. 18, no. 3, 1988, pp. 291-00, https://doi.org/10.1080/00397918808057836.

Genre

  • Journal Article
Contributors
Author: Sutherland, Ronald G.
Author: Piorko, Adam
Author: Lee, Choi Chuck
Author: Abd-El-Aziz, Alaa S.
Date Issued
1988
Abstract

Reaction of an η6-chloroarene-η5-cyclopentadienyl-iron hexafluorophosphate with diethyl malonate in the presence of K2CO3 in THF/DMSO gave a corresponding SN-Ar product, η6-diethyl arylmalonate-η5-cyclopentadienyliron hexafluorophosphate, which, upon pyrolytic sublimation, resulted in the liberation of the arylated malonic ester. Such esters prepared in the present work included RPhCH(COOEt)2, with R = o-, m- or p-CH3, 2,6-(CH3)2, or o-, m- or p-Cl2.

Note

Dep. Chem., Univ. Saskatchewan, Saskatoon, SK, Can.

Source type: Electronic(1)

Language

  • English

Subjects

  • chlorobenzenecyclopentadienyliron
  • malonate
  • diethyl
  • chlorobenzene
  • Ferrocene
  • EXCHANGE
  • Arylation (of malonate ester by (chlorobenzene)cyclopentadienyliron hexafluorophosphates)
  • arylation
  • phenylmalonate
Page range
291-300
Host Title
Synthetic Communications
Host Abbreviated Title
Synth. Commun.
Volume
18
Issue
3
ISSN
0039-7911
DOI
https://doi.org/10.1080/00397918808057836

Department