Afifi, Tarek H., et al. “First Example of Benzothiazole Azo Dyes Containing Cyclopentadienyliron Polynorbornene Macromolecules”. Journal of Inorganic and Organometallic Polymers, vol. 14, no. 4, 2004, pp. 269-78, https://doi.org/10.1023/B:JOIP.0000048031.82464.ac.

Genre

  • Journal Article
Contributors
Author: Afifi, Tarek H.
Author: Okasha, Rawda M.
Author: Abd-El-Aziz, Alaa S.
Date Issued
2004
Abstract

Soluble cationic organoiron polynorbornenes with pendent hetarylazo side chains have been synthesized via ring opening metathesis polymerization (ROMP) using bis(tricyclohexylphosphine)benzylideneruthenium(IV) dichloride (Grubbs' catalyst). The vibrantly colored organoiron polymers displayed weight average molecular weights between 24500 and 40900 and exhibited glass transition temperatures at 146 °C and 161 °C.

Note

Department of Chemistry, The University of Winnipeg, Winnipeg, MB, Can.

Language

  • English

Subjects

  • prepn
  • ring
  • Glass transition temperature (of polymers of benzothiazole azo dyes contg. cyclopentadienyliron polynorbornene macromols.)
  • for prepn. of benzothiazole azo dyes contg. cyclopentadienyliron polynorbornene macromols.)
  • norbornadiene
  • polymn
  • prepn. of benzothiazole azo dyes contg. cyclopentadienyliron polynorbornene macromols.)
  • Azo dyes (polymerizable
  • UV and visible spectra (of benzothiazole azo dyes contg. cyclopentadienyliron polynorbornene macromols.)
  • azo
  • opening
  • dye
  • organoiron
Page range
269-278
Host Title
Journal of Inorganic and Organometallic Polymers
Host Abbreviated Title
J. Inorg. Organomet. Polym.
Volume
14
Issue
4
ISSN
1053-0495

Department