Valorization of the spent catalyst from flue gas denitrogenation by improving bio-oil production from hydrothermal liquefaction of pinewood sawdust

Normally, the spent catalyst (V2O5-WO3/TiO2, denoted as VWTi) is dumped as a solid waste after denitrogenation of flue gas through selective catalyst reduction (SCR). However, this used catalyst contains an abundant amount of acid sites and thus can be potentially utilized as the catalyst in hydrothermal liquefaction (HTL) to produce bio-oil. Thus, in this study, the influences of operational variables on the main HTL products distribution and physicochemical properties of bio-oil were evaluated at 240–320 °C for 0–60 min and 0–20 wt% of catalyst dosage. The results demonstrated that the spent VWTi catalyst significantly promoted the production of bio-oil, yielding the highest bio-oil yield (33.9 wt%) at 300 °C for 30 min with a 10 wt% of catalyst loading. The bio-oil obtained with catalyst under the optimal conditions has a HHV of 28.69 MJ/kg, along with an energy recovery of 51.93%. In addition, the use of the spent VWTi catalyst in the HTL could obtain a higher fraction of phenolics compounds with lower boiling point and lower molecular weight, as identified by TGA and GPC analysis. Overall, this study provides an alternative route to valorize the spent catalyst from flue gas denitrogenation by applying as a catalyst to produce high quality bio-oil production in the biomass HTL process.