Genre
- Journal Article
C-60 acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the photolysis of 3-chloro-3-isopropyldiazirine and 3-chloro-3-chloromethyldiazirine. The carbene adds to C-60 to form methanofullerene, whereas the diazo compound adds to C-60 to form fulleroid. The olefin product arises as a result of the rearrangement in the excited state.
Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan. Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan. Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada. Inst Mol Sci, Dept Theoret Studies, (TRUNCATED)
WASHINGTON; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
AMER CHEMICAL SOC
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Source type: Electronic(1)
Language
- English
Subjects
- EXCHANGE
- HYDROGEN MIGRATION
- ALKYLCHLOROCARBENES
- Chemistry, Multidisciplinary
- DIAZIRINES
- C-60