Genre
- Journal Article
Reaction of arylchlorodiazirines with trimethylenesulfide gives a mixture of aryldi(3-chloropropyl)thioacetal and aryl(2-propenyl)(3-chloropropyl)thioacetal in a good yield. The reaction goes through a formation of a sulfur ylide as an intermediate. Rate constants have been determined using laser flash photolytic techniques. (C) 2000 Elsevier Science Ltd. All rights reserved.
Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada. Univ Bordeaux 1, LPCM, Lab Chim Phys A, F-33405 Talence, France.; Liu, MTH, Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada.
OXFORD; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
PERGAMON-ELSEVIER SCIENCE LTD
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Source type: Electronic(1)
Language
- English
Subjects
- METAL CARBENE TRANSFORMATIONS
- sulfur ylide
- thioacetal
- diazirine
- REARRANGEMENT
- laser flash photolysis
- CARBENE
- trimethylene sulfide
- Chemistry, Organic
- Kinetics