Genre
- Journal Article
p-Chlorophenylchlorocarbene reacts with allyl bromide to form the expected cyclopropanes. In the case of p-nitrophenylchlorocarbene, a small amount of insertion product is also formed in addition to the cycloadducts. The formation of the insertion product is attributed to the attack of the carbene on the bromine atom followed by intramolecular allylic rearrangement.
UNIV PRINCE EDWARD ISL,DEPT CHEM,CHARLOTTETOWN C1A 4P3,PE,CANADA. OSAKA UNIV,COLL GEN EDUC,INST CHEM,TOYONAKA,OSAKA 560,JAPAN.; BONNEAU, R, UNIV BORDEAUX 1,CHIM PHYS LAB A,CNRS,URA 348,F-33405 TALENCE,FRANCE.
ZEIST; PO BOX 346, 3700 AH ZEIST, NETHERLANDS
VSP BV
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Source type: Electronic(1)
Language
- English
Subjects
- Chemistry, Multidisciplinary
- SULFIDES
- MECHANISM