Rodriguez, J., et al. “Cyclobutenbriarein A, the First Diterpene With a Tricyclo[8.4.0.0(3,6)]tetradec-4-Ene Ring System Isolated from the Gorgonian Briareum Asbestinum”. The Journal of Organic Chemistry, vol. 67, no. 15, 2002, pp. 5117-23, https://scholar2.islandarchives.ca/islandora/object/ir%3Air-batch6-434.

Genre

  • Journal Article
Contributors
Author: Rodriguez, J.
Author: Kerr, Russell G.
Author: Jimenez, C.
Author: Gonzalez, N.
Date Issued
2002
Abstract

Cyclobutenbriarein A (2), a novel class of C20-rearranged diterpene briarane possessing an unprecedented tricyclo[8.4.0.0(3,6)]tetradec-4-ene ring system was isolated, along with five new briarane diterpenoids (1 and 3-6), from the organic extracts of the Bahamian gorgonian Briareum asbestinum. The structures of these secondary metabolites were established on the basis of extensive NMR studies and accurate mass measurements (HRFABMS).

Note

Departamento de Quimica Fundamental, Facultade de Ciencias, Universidade de A Coruna, 15071 A Coruna, Spain.

United States

LR: 20061115; PUBM: Print; JID: 2985193R; 0 (Diterpenes); 0 (cyclobutenbriarein A); EIN: J Org Chem. 2003 Dec 12;68(25):9874; ppublish

Source type: Electronic(1)

Language

  • English

Subjects

  • animals
  • cyclization
  • Cnidaria/chemistry
  • Bahamas
  • Nuclear Magnetic Resonance, Biomolecular
  • Crystallography, X-Ray
  • Diterpenes/chemistry/isolation & purification
  • Molecular Structure
  • Molecular Conformation
Page range
5117-5123
Host Title
The Journal of Organic Chemistry
Host Abbreviated Title
J.Org.Chem.
Volume
67
Issue
15
ISSN
0022-3263

Department