Genre
- Journal Article
The structures of trans-[Co-III(cyclam)(NCS)(2)](NCS) and of [Co-II(Me(4)cyclam)(NCS)](2)[Co(NCS)(4)]. MeOH have been established by X-ray diffraction methods. The solvatochromic behavior of the trans-[Co(cyclam)(NCS)(2)](+) cation in several binary aqueous solvent mixtures is reported. Transfer chemical potentials for this complex from H2O into MeOH-H2O mixtures have been established from solubility measurements on its thiocyanate salt. The solvatochromic behavior of this cation is discussed in the context of other solvatochromic inorganic complexes; its transfer chemical potentials are discussed in relation to those of other cobalt(III) complexes.
Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England.; Fawcett, J, Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England.
DORDRECHT; SPUIBOULEVARD 50, PO BOX 17, 3300 AA DORDRECHT, NETHERLANDS
KLUWER ACADEMIC PUBL
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Source type: Electronic(1)
Language
- English
Subjects
- SOLUBILITIES
- COBALT(III)
- CRYSTAL-STRUCTURE
- CHROMIUM(III)
- iron(II)
- COMPLEXES
- WATER
- Chemistry, Inorganic & Nuclear
- SOLVENT POLARITY
- AQUEOUS METHANOL
- TRANSFER CHEMICAL-POTENTIALS