Genre
- Journal Article
Dependences of rate constants on pressure (in aqueous solution up to 1.25 kbar) are reported for peroxodisulphate oxidation of hexacyanoferrate(TI), tris(2,2'-bipyridyl)iron(II), tris(l,10-phenanthroline)iron(II), bis(l,4,7-triazacyclononane)nickel(II) and bis(l,2-ethanediamine)cysteinatocobalt(III) and its thioglycollato-analogue, and for periodate oxidation of the two last-named complexes. Derived activation volumes are reported and discussed in terms of intrinsic and solvational contributions. Rate laws and pressure effects on reactivity are reported for the reaction of peroxodisulphate with pentacyanoferrates(II) containing N-alkylpyrazinium ligands.
UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND. COMENIUS UNIV BRATISLAVA,DEPT PHYS CHEM,CS-84215 BRATISLAVA,CZECHOSLOVAKIA. MEM UNIV NEWFOUNDLAND,SIR WILFRED GRENFELL COLL,CORNER BROOK A2H 6P9,NF,CANADA.
LONDON; 2-6 BOUNDARY ROW, LONDON, ENGLAND SE1 8HN
CHAPMAN HALL LTD
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Source type: Electronic(1)
Language
- English
Subjects
- REDOX REACTIONS
- Chemistry, Inorganic & Nuclear
- ION
- Kinetics