Nikawa, Hidefumi, et al. “Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Ingle Crystal X-Ray Structure of the Carbene Adduct”. Journal of the American Chemical Society, vol. 130, no. 39, 2008, pp. 12840-1, https://doi.org/10.1021/ja802156n.

Genre

  • Journal Article
Contributors
Author: Nikawa, Hidefumi
Author: Ishitsuka, Midori O.
Author: Akasaka, Takeshi
Author: Liu, Michael T. H.
Author: Tsuchiya, Takahiro
Author: Kato, Tatsuhisa
Author: Mizorogi, Naomi
Author: Nagase, Shigeru
Author: Slanina, Zdenek
Author: Yoza, Kenji
Author: Kono, Takayoshi
Author: Takematsu, Yuji
Author: Maeda, Yutaka
Author: Nakahodo, Tsukasa
Author: Wakahara, Takatsugu
Author: Yamamoto, Kazunori
Date Issued
2008
Abstract

Abstract: We report here the results on single crystal X-ray crystallographic analysis of the Gd@C82 carbene adduct (Gd@C82(Ad), Ad = adamantylidene). The Gd atom in Gd@C82(Ad) is located at an off-centered position near a hexagonal ring in the C2v-C82 cage, as found for M@C82 (M = Sc and La) and La@C82(Ad). Theoretical calculation also confirms the position of the Gd atom in the X-ray crystal structure.

Note

Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba 305-8577, Japan, Department of Chemistry, Tokyo Gakugei University, Koganei 184-8501, Japan, Department of Chemistry, University of Prince Edward Island, Prince Edward Island C1A4P3, Canada, Bruker AXS K. K., Yokohama 221-0022, Japan, Department of Chemistry, Josai University, Sakado 171-8501, Japan, Japan Atomic Energy Agency, Tokai 319-1100, Japan, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki 444-8585, Japan

Source type: Electronic(1)

Language

  • English
Rights
Contact Publisher
Page range
12840-12841
Host Title
Journal of the American Chemical Society
Host Abbreviated Title
J. Am. Chem. Soc.
Volume
130
Issue
39
ISSN
0002-7863
DOI
https://doi.org/10.1021/ja802156n